Skip to main content

Official Journal of the Japan Wood Research Society

  • Original Article
  • Published:

Piezoelectric effect of cyanoethylated hydroxyethylcellulose

Abstract

The piezoelectricity of cyanoethylated hydroxyethylcellulose was investigated. Elastic, piezoelectric, and dielectric relaxations were observed at −80° to −60°C and 0° to 20°C at a frequency of 10Hz. The activation energy is about 9–15 kcal/mol in the low temperature region and about 30–45 kcal/mol at room temperature. These relaxations in the low temperature region may be caused by the motion of the cyanoethyl group and those at room temperature mostly by the motions of the main chain. Cyanoethylated hydroxyethylcellulose has a high piezoelectric strain constant (d 25), which is the largest value among the cellulose derivatives and is almost the same as the value for polyvinylidene fluoride. The electromechanical coupling factor for cyanoethylated hydroxyethylcellulose was small.

References

  1. Furukawa T (1977) Doctoral thesis, University of Tokyo, pp 99–100

  2. Ohigashi H (1975) Electromechanical properties of polarized polyvinylidene fluoride films as studied by the piezoelectric resonance method. J Appl Phys 47:949–955

    Article  Google Scholar 

  3. Cohen SG, Haas HC (1950) Studies on the structure of hydroxyethylcellulose. J Am Chem Soc 72:3954–3958

    Article  CAS  Google Scholar 

  4. Lewis CW, Holgle DH (1956) The Rotation of Polar Groups in High Polymers J Polymer Sci 21:411–416

    Article  CAS  Google Scholar 

  5. Suzuki K (1994) Synthesis of cyanoethylated cellulose derivatives Report of grant-in-aid for scientific research (C), p 4 (head investigator N. Hirai)

  6. Sobue N, Hirai N, Asano I (1971) Studies on structure of wood by X-ray. II. Mokuzai Gakkaishi 17:44–50

    Google Scholar 

  7. Hirai N, Morita M, Suzuki Y (1993) Electrical properties of cyanoethylated wood meal and cyanoethylated cellulose. Mokuzai Gakkaishi 39:603–609

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hirai, N., Ootake, K., Suzuki, K. et al. Piezoelectric effect of cyanoethylated hydroxyethylcellulose. J Wood Sci 44, 35–39 (1998). https://doi.org/10.1007/BF00521872

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00521872

Key words