Skip to main content
Download PDF
  • Original Article
  • Published:

Studies on the synthesis and properties of terpene-phenol-aldehyde resin with a high softening point

Journal of Wood Science volume 46, pages 143–148 (2000)Cite this article

Abstract

Synthesis conditions of terpene-phenol-aldehyde resin with a high softening point were studied based on the reactions amongα-pinene, phenol, and formaldehyde. A suitable catalyst system and the best processing conditions were obtained by laboratory experiments. The influence of the raw materials ratios, reaction temperature, reaction time, and catalyst dose on the softening point, yield, and color of the synthesized resin was examined. The physical and chemical characteristics of the resin were determined: softening point ≥140°C (ball and ring method); color value ≤7 (Gardner); acid value (KOH mg/g) <1; bromine value (Br2 mg/100g) <64; saponification value (KOH mg/g) <1; average molecular weight ∼830. The yield of resin was more than 85% (based on the total raw material).

References

  1. Mamfred G, Karl H (1976) Terpene-phenol resins. Ger Offen 2,616,592, October 28, 1976

  2. Gajduchenya Galina M, Kirasirova Valentina N (1993) Formaldehyde-phenol-terpene resin coatings (in Russian). Izobreteniya 5:56

    Google Scholar 

  3. Rizzer Alexander J (1973) Composition of sealing joint. US 3,759,780, September 18, 1973

  4. Bublik AT, Vlasov VI, Gavrilushkina FS, Zhukova AF, Kreindei MY, Kuprina LB, Nesterova ET. Nesterov AS (1988) Sealing compound (in Russian). Otkrytiya Izobret 14:118

    Google Scholar 

  5. Sasaki T, Noguchi K (1994) Terpene-modified phenol resin aqueous emulsion compositions (in Japanese). Jpn Kokai Tokkyo Koho JP 08,100,104, April 16, 1994

  6. Boutillier J, Dehay G, Fonction N, Leroux R (1986) Assembling surfaces by applying a polyurethane or polyether amide joint, superficially melting this joint and cooling it. Eur Pat Appl EP 197,845, October 15, 1986

  7. Nesterova ET, Kuprina LB, Borovkoa NN (1985) Production of terpenic phenol-formaldehyde resin from monoterpene hydrocarbons (in Russian). Gidroliz Lesokhim Prom-st 1:15–16

    Google Scholar 

  8. Fukui T, Sakamoto T, Fujita N (1979) Manufacture of phenolic resins (in Japanese). Jpn Kokai Tokkyo Koho 79,116,080, September 10, 1979

  9. Yurasov PF, Zyuzyun VE (1984) New type of products at the Verkhoture Wood-chemical Plant (in Russian). Gidroliz Lesokhim Prom-st 8:24–25

    Google Scholar 

  10. Lin J, Ma CZ (1989) Synthesis of terpene-phenol-aldehyde resin (in Chinese). Sci Techn For Chem 3:23–25

    Google Scholar 

  11. National standard of terpene-phenol resin (in Chinese). 1992

  12. Yuan YZ, Cheng Z (1989) Preparation of terpene phenolic resin (in Chinese). J Nanjing For Univ 13(1):22–31

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Science and Engineering, Shimane University, 690-8504, Matsue, Japan

    Shi-Fa Wang & Takeshi Furuno

  2. College of Chemical Engineering of Forest Products, Nanjing Forestry University, 210037, Nanjing, China

    Shi-Fa Wang & Zhi Cheng

Authors
  1. Shi-Fa Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Takeshi Furuno
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zhi Cheng
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, SF., Furuno, T. & Cheng, Z. Studies on the synthesis and properties of terpene-phenol-aldehyde resin with a high softening point. J Wood Sci 46, 143–148 (2000). https://doi.org/10.1007/BF00777361

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00777361

Key words