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Official Journal of the Japan Wood Research Society

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Changes in micropores in dry wood with elapsed time in the environment

Abstract

To investigate the changes in microstructures of wood with elapsed time in the environment, CO2 adsorption onto dry wood was measured at ice-water temperature (273 K) for samples aged from 0.1 years to over 1000 years. The micropore size distribution was obtained using the Horvath-Kawazoe method. Micropores smaller than 0.6 nm in wood decreased in number with elapsed time in the environment, and a negative correlation was found between cumulative pore volume for pores smaller than 0.6 nm and elapsed time in the environment. Cumulative pore volume in the 1000-year sample was almost half of that in the 0.1- year sample. Micropores smaller than 0.6 nm in wood with a few decades or more of elapsed time increased in number after rewetting and drying. Consequently, microstructures of wood with longer time elapsed in the environment were considered to be more stable, because of longer-term thermal motion and possibly more repeated moisture adsorption and desorption and/or temperature variation in the environment.

References

  1. Kohara J (1958) Study on the old timber. Res Rep Fac Eng Chiba Univ 9(15):1–55

    Google Scholar 

  2. Kohara J (1958) Study on the old Timber. Res Rep Fac Eng Chiba Univ 9(16):23–65

    Google Scholar 

  3. Hirashima Y, Sugihara M, Sasaki Y, Ando K, Yamasaki M (2004) Strength properties of aged wood I. Tensile strength properties of aged keyaki and akamatsu woods (in Japanese). Mokuzai Gakkaishi 50:301–309

    CAS  Google Scholar 

  4. Hirashima Y, Sugihara M, Sasaki Y, Ando K, Yamasaki M (2004) Strengh properties of aged wood II. Compressive strength properties, shearing strength and hardness of aged keyaki and akamatsu woods (in Japanese). Mokuzai Gakkaishi 50:368–375

    CAS  Google Scholar 

  5. Hirashima Y, Sugihara M, Sasaki Y, Ando K, Yamasaki M (2005) Strength properties of aged wood III. Static and impact bending strength properties of aged keyaki and akamatsu woods (in Japanese). Mokuzai Gakkaishi 51:146–152

    Article  CAS  Google Scholar 

  6. Ando K, Hirashima Y, Sugishita M, Hirao S, Sasaki Y (2006) Microscopic processes of shearing fracture of old wood, examined using the acoustic emission technique. J Wood Sci 52:483–489

    Article  Google Scholar 

  7. Furuta Y, Norimoto M, Yano H (1998) Thermal-softening properties of water-swollen wood V. The effects of drying and heating histories (in Japanese). Mokuzai Gakkaishi 44:82–88

    CAS  Google Scholar 

  8. Kudo M, Iida I, Ishimaru Y, Furuta Y (2003) The effect of quenching on the mechanical properties of wet wood (in Japanese). Mokuzai Gakkaishi 49:253–259

    Google Scholar 

  9. Kamei K, Ishimaru Y, Iida I, Furuta Y (2004) Effect of sample preparation methods on mechanical properties of wood I (in Japanese). Mokuzai Gakkaishi 50:10–17

    CAS  Google Scholar 

  10. Ishimaru Y (2003) Mechanical properties of wood in unstable states caused by changes in temperature and/or swelling. Proceedings of the 2nd International Conference of the European Society for Wood Mechanics, Stockholm, pp 69–78

  11. Takahashi C, Ishimaru Y, Iida I, Furuta Y (2006) The creep of wood destabilized by change in moisture content. Part 3: the influence of changing moisture history on creep behavior. Holzforschung 60:299–303

    CAS  Google Scholar 

  12. Nakano T (2005) Effects of quenching on relaxation properties of wet wood. J Wood Sci 51:112–117

    Article  Google Scholar 

  13. Kojiro K, Furuta Y, Ishimaru Y (2008) Influence of histories on dynamic viscoelastic properties and dimensions of water-swollen wood. J Wood Sci 54:95–99

    Article  Google Scholar 

  14. Kovacs AJ (1964) Transition vitreuse dans les polymers amorphes. Etud Phenomenol Hochpolym Forsch 3:394–507

    Article  CAS  Google Scholar 

  15. Struik LCE (1978) Physical aging in amorphous polymers and other materials. Elsevier, Amsterdam

    Google Scholar 

  16. Kojiro K, Furuta Y, Ishimaru Y (2008) Influence of heating history on dynamic viscoelastic properties and dimensions of dry wood. J Wood Sci 54:196–201

    Article  Google Scholar 

  17. Kojiro K, Furuta Y, Ishimaru Y (2008) Influence of heating and drying history on micropores in dry wood. J Wood Sci 54: 202–207

    Article  Google Scholar 

  18. Harvath G, Kawazoe K (1983) Method for the calculation of effective pore size distribution in molecular sieve carbon. J Chem Eng Jpn 16:470–475

    Article  Google Scholar 

  19. Yokoyama M (2007) Establishment of database for the aging wood from Japanese historical buildings. Proceedings of the 65th RISH Symposium, Kyoto, pp 16–25

  20. Nakatani T, Ishimaru Y, Iida I, Furuta Y (2008) Micropore structure of wood: change in micropore distribution according to delignification J Wood Sci 54:252–255

    Article  CAS  Google Scholar 

  21. Goring DAI (1963) Thermal softening of lignin, hemicellulose and cellulose. Pulp Pap Canada 64:T517–527

    CAS  Google Scholar 

  22. Nakatani T, Ishimaru Y, Iida I, Furuta Y (2008) Contribution of lignin on adsorption of organic liquids onto wood (in Japanese). Mokuzai Gakkaishi 54:17–23

    Article  CAS  Google Scholar 

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Correspondence to Keisuke Kojiro.

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Kojiro, K., Furuta, Y., Ohkoshi, M. et al. Changes in micropores in dry wood with elapsed time in the environment. J Wood Sci 54, 515–519 (2008). https://doi.org/10.1007/s10086-008-0973-5

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  • DOI: https://doi.org/10.1007/s10086-008-0973-5

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