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Reaction behavior of wood in an ionic liquid, 1-ethyl-3-methylimidazolium chloride
Journal of Wood Science volume 55, pages 215–219 (2009)
Abstract
Reaction of Japanese beech (Fagus crenata) in an ionic liquid, 1-ethyl-3-methylimidazolium chloride ([C2mim][Cl]), which can dissolve cellulose, was investigated. Although both lignin and polysaccharides such as cellulose and hemicelluloses can be liquefied at a treatment temperature of around 100°C, the liquefaction of polysaccharides mainly occurs at the beginning of the treatment with [C2mim][Cl]. Cellulose crystallinity in the wood was gradually broken down as the treatment continued. The solubilized polymers were depolymerized to low molecular weight compounds. The results indicate that [C2mim][Cl] is an effective solvent and reagent for the liquefaction of wood components and subsequent depolymerization of them.
References
Goldstein IS (1980) The hydrolysis of wood. TAPPI 63:141–143
Chang VS, Holtzapple MT (2000) Fundamental factors affecting biomass enzymatic reactivity. Appl Biochem Eng Biotechnol 38:53–87
Mok WS, Antal MJ Jr (1992) Uncatalyzed solvolysis of whole biomass hemicelluloses by hot compressed liquid water. Ind Eng Chem Res 31:1157–1161
Saka S, Konishi R (2001) Chemical conversion of biomass resources to useful chemicals and fuels by supercritical water treatment. In: Bridgewater AV (ed) Progress in thermochemical biomass conversion. Blackwell, Oxford, pp 1338–1348
Yamazaki J, Minami E, Saka S (2006) Liquefaction of beech wood in various supercritical alcohols. J Wood Sci 52:527–532
Kwon GJ, Kuga S, Hori K, Yatagai M, Ando K, Hattori N (2006) Saccharification of cellulose by dry pyrolysis. J Wood Sci 52:461–465
Hosoya T, Kawamoto H, Saka S (2007) Influence of inorganic matter on wood pyrolysis at gasification temperature. J Wood Sci 53:351–357
Sheldon R (2001) Catalytic reaction in ionic liquids. Chem Commun 2399–2407
Zulfiqar F, Kitazume T (2000) One-pot aza-Diels-Alder reaction in ionic liquids. Green Chem 2:137–139
Swatloski RP, Spear SK, Hobrey JD, Rogers RD (2002) Dissolution of cellulose with ionic liquids. J Am Chem Soc 124:4947–4975
Turner MB, Spear SK, Hobrey JD, Rogers RD (2004) Production of bioactive cellulose films reconstituted from ionic liquids. Biomacromolecules 5:1379–1384
Heinze T, Schwikal K, Barthel S (2005) Ionic liquids as reaction medium in cellulose functionalization. Macromol Biosci 5:520–525
Wu J, Zhang J, He J, Ren Q, Guo M (2004) Homogeneous acetylation of cellulose in a new ionic liquid. Biomacromolecules 5:266–268
Cao Y, Wu J, Meng T, Zhang J, He J, Li H, Zhang Y (2007) Acetone-soluble cellulose acetates prepared by one-step homogeneous acetylation of cornhusk cellulose in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). Carbohydr Polym 69:665–672
Schlufter K, Schmauder H-P, Dorn S, Heinze T (2006) Efficient homogeneous chemical modification of bacterial cellulose in the ionic liquid 1-n-butylimidazolium chloride. Macromol Rapid Commun 27:1670–1676
Barthel S, Heinze T (2006) Acylation and carbanilation of cellulose in ionic liquids. Green Chem 8:301–306
Liu CF, Sun RC, Zhang AP, Ren JL, Wang XA, Qin MH, Chao ZN, Luo W (2007) Homogeneous modification of sugarcane bagasse cellulose with succinic anhydride using an ionic liquid as reaction medium. Carbohydr Res 342:919–926
Liu CF, Sun RC, Zhang AP, Qin MH, Ren JL, Wang XA (2007) Preparation and characterization of phthalated cellulose derivatives in room-temperature ionic liquid without catalysts. J Agr Food Chem 55:2399–2406
Xie H, Shi T (2006) Wood liquefaction by ionic liquid. Holzforschung 60:509–512
Kilpeläinen I, Xie H, King A, Granstrom M, Heikkinen S, Argyropoulos DS (2007) Dissolution of wood in ionic liquids. J Agr Food Chem 55:9142–9148
Pu Y, Jiang N, Ragauskas AJ (2007) Ionic liquid as a green solvent for lignin. J Wood Chem Technol 27:23–33
Dence CW (1992) The determination of lignin. In: Lin SY, Dence CW (eds) Methods in lignin chemistry. Springer, Berlin Heidelberg New York, pp 33–39
Kubo S, Hashida K, Hosoya S, Yamada T, Magara K, Kishino M, Ohno H (2007) Solubility of wood and stability of lignin model compounds in ionic liquid (in Japanese). Proceedings of 52nd Lignin Symposium, Utsunomiya, pp 134–137
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Miyafuji, H., Miyata, K., Saka, S. et al. Reaction behavior of wood in an ionic liquid, 1-ethyl-3-methylimidazolium chloride. J Wood Sci 55, 215–219 (2009). https://doi.org/10.1007/s10086-009-1020-x
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DOI: https://doi.org/10.1007/s10086-009-1020-x