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Official Journal of the Japan Wood Research Society

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Pyrolysis GC-MS analysis of tars formed during the aging of wood and bamboo crude vinegars

Abstract

Constituents of tars formed during the aging of bamboo (Phyllostachys pubescens), oak (Quercus serrata), and pine (Pinus densiflora) wood crude vinegars were analyzed by pyrolysis-gas chromatography (Py-GC) and pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) to investigate their origination. The pyrolysate of tars obtained from the wood and bamboo crude vinegars were almost identical and were primarily composed of phenolic compounds and aromatic hydrocarbons. In addition, during the aging of model wood vinegar that was prepared for comparison with the wood and bamboo vinegars, a marked decrease was observed in the levels of phenolic compounds (phenol; o-, p-, and m-cresol; and syringol). Furthermore, the Py-GC-MS results of the tars produced during the aging of the model wood vinegar revealed that phenolic compounds were primarily responsible for the formation of tar during the aging of wood and bamboo crude vinegars. Pyrroles, which may be derived from the primary pyrolysate of amino acids, nitrogen-containing extracts, or both, were also partially involved in the formation of tar during the aging period.

References

  1. Yatagai M, Unrinin G, Ohira T (1988) By-products of wood carbonization IV: components of wood vinegars. Mokuzai Gakkaishi 34:184–188

    CAS  Google Scholar 

  2. Yasuhara A (1987) Volatile compounds in pyroligneous liquids from Karamatu and Chisima-sasa. Agric Bio Chem 51:3049–3060

    CAS  Google Scholar 

  3. Yatagai M, Unrinin G (1987) By-products of wood carbonization III: germination and growth acceleration effects of wood vinegars on plant seeds. Mokuzai Gakkaishi 33:521–529

    CAS  Google Scholar 

  4. Yatagai M, Unrinin G (1989) By-products of wood carbonization VI: germination and growth effects of wood vinegar components and their homologs on plant seeds: alcohols and phenols. Mokuzai Gakkaishi 35:1021–1028

    CAS  Google Scholar 

  5. Mu J, Uehara T, Furuno T (2004) Effect of bamboo vinegar on regulation of germination and radicle growth of seed plants II: composition of moso bamboo vinegar at different collection temperatures and its effects. J Wood Sci 50:470–476

    Article  CAS  Google Scholar 

  6. Mu J, Uehara T, Furuno T (2003) Effect of bamboo vinegar on regulation of germination and radicle growth of seed plants. J Wood Sci 49:262–270

    Article  CAS  Google Scholar 

  7. Yatagai M, Unrinin G, Sugiura G (1986) By-products of wood carbonization: tars from mangrove, sugi ogalite, wheat straw, and Chishima-sasa. Mokuzai Gakkaishi 32:467–471

    CAS  Google Scholar 

  8. Yatagai M, Takahashi T, Sakita MN (1986) By-products of wood carbonization II: wood tars from the trees of Brazil. Mokuzai Gakkaishi 32:626–631

    CAS  Google Scholar 

  9. Del Rio JC, Gutiérrez A, Romero JM, Martínez J, Martínez AT (2001) Identification of residual lignin markers in eucalypt kraft pulps by Py-GC/MS. J Anal Appl Pyrol 59:425–439

    Article  Google Scholar 

  10. Mun SP, Ku CS, Park SB (2007) Physicochemical characterization of pyrolysates produced from carbonization of lignocellulosic biomass in a batch-type mechanical kiln. J Ind Eng Chem 13:127–132

    CAS  Google Scholar 

  11. Park SB, Kwon SD (1998) Development of new uses of bamboo (II) — development of carbonization kiln and schedule investigation for bamboo charcoal making. KFRI J For Sci 59:17–24

    Google Scholar 

  12. Park SB, Kwon SD, Kim YK, Koo JO (2002) Development of new uses of bamboo (IV) — development of recovery system of bamboo vinegar and its properties. KFRI J For Sci 65:87–96

    Google Scholar 

  13. Ku CS, Mun SP, Park SB, Kwon SD (2002) Physicochemical changes of vinegars obtained from bamboo and wood during long-term aging. Mokchae Konghak 30:74–79

    Google Scholar 

  14. Faix O, Meier D, Formann I (1990) Thermal degradation products of wood: gas chromatographic separation and mass spectrometric characterization of monomeric lignin-derived products. Holz als Roh- und Werkstoff 48:281–285

    Article  CAS  Google Scholar 

  15. Faix O, Meier D, Formann I (1990) Thermal degradation products of wood: a collection of electron-impact (EI) mass spectra of monomeric lignin-derived products. Holz als Roh- und Werkstoff 48:351–354

    Article  CAS  Google Scholar 

  16. Nakamura T, Kawamoto H, Saka S (2007) Condensation reactions of some lignin-related compounds at relatively low pyrolysis temperature. J Wood Chem Technol 27:121–133

    Article  CAS  Google Scholar 

  17. Hosoya T, Kawamoto H, Saka S (2008) Different pyrolytic pathways of levoglucosan in vapor- and liquid/solid-phases. J Anal Appl Pyrol 83:78–87

    Article  CAS  Google Scholar 

  18. Jodai S, Yano S, Uehara T (1989) Components of wood vinegar liquors and their smoke flavors. Mokuzai Gakkaishi 35:555–563

    CAS  Google Scholar 

  19. Mun SP, Ku CS (2002) Analysis of volatile compounds in bamboo and wood crude vinegars by the solid-phase microextraction (SPME) method. Mokchae Konghak 30:80–86

    Google Scholar 

  20. McGrath TE, Chan WG, Hajaligol MR (2003) Low-temperature mechanism for the formation of polycyclic aromatic hydrocarbons from the pyrolysis of cellulose. J Anal Appl Pyrol 66:51–70

    Article  CAS  Google Scholar 

  21. Herring A, McKinnon J, Petrick D, Gneshin K, Filley J, McCloskey B (2003) Detection of reactive intermediates during laser pyrolysis of cellulose char by molecular beam mass spectroscopy, implications for the formation of polycyclic aromatic hydrocarbons. J Anal Appl Pyrol 66:165–182

    Article  CAS  Google Scholar 

  22. Britt PF, Buchanan AC III, Kidder MK, Owens CV Jr (2003) Influence of steroid structure on the pyrolytic formation of polycyclic aromatic hydrocarbons. J Anal Appl Pyrol 66:71–95

    Article  CAS  Google Scholar 

  23. Sharma RK, Hajaligol MR (2003) Effect of pyrolysis conditions on the formation of polycyclic aromatic hydrocarbons (PAHs) from polyphenolic compounds. J Anal Appl Pyrol 66:123–144

    Article  CAS  Google Scholar 

  24. Coleman WM III, Chung HL (2002) Pyrolysis GC-MS analysis of Amadori compounds derived from selected amino acids and glucose. J Anal Appl Pyrol 62:215–223

    Article  CAS  Google Scholar 

  25. Coleman WM III, Chung HL (2002) Pyrolysis GC-MS analysis of Amadori compounds derived from selected amino acids with glucose and rhamnose. J Anal Appl Pyrol 63:349–366

    Article  CAS  Google Scholar 

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Mun, S.P., Ku, C.S. Pyrolysis GC-MS analysis of tars formed during the aging of wood and bamboo crude vinegars. J Wood Sci 56, 47–52 (2010). https://doi.org/10.1007/s10086-009-1054-0

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  • DOI: https://doi.org/10.1007/s10086-009-1054-0

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