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Official Journal of the Japan Wood Research Society

Table 2 List of pseudo-first-order reaction rate constants (k) of the disappearance of compound II in solutions 1, 2, 3, 4, 5, and 6 as well as Arrhenius activation energies (E a) and Arrhenius frequency factors (A) of the disappearance of compound II in solutions 1, 2, and 3

From: Synergistic contribution of hydrosulfide and carbonate anions to the β-O-4 bond cleavage of lignin model compounds in a green liquor pretreatment for enzymatic hydrolysis of lignocellulosic materials

Solution

1

2

3 a

4

5

6

k b

 140 °C

4.88

6.51

11.40

 150 °C

10.90

18.10

24.60

 160 °C

29.60

35.90

45.50

3.74

6.47

28.30

E a (kJ/mol)

135

128

104

A (per min)

4.02 × 1014

8.39 × 1012

1.06 × 1010

  1. aSolution 3 was a model solution of GL
  2. bUnit: ×10−4/min