Skip to main content

Official Journal of the Japan Wood Research Society

Table 1 Reaction conditions for preparation of cationized glycol lignin and nitrogen content of the cationized glycol lignin

From: Preparation of flocculant for optimizing glycol lignin manufacturing process by cationization of glycol lignin

Cationized glycol lignin

Reaction conditions

Reaction product

Raw material

GTA

Treatment

N content

Glycol lignin

(g)

(mL)

after reaction

(%)

P200G1

PEG200-lignin

1.0

3.0

Dialysis

2.3

P200G2

PEG200-lignin

1.0

1.0

Dialysis

1.7

P200G3

PEG200-lignin

3.0

1.0

Dialysis

1.5

P200G4

PEG200-lignin

3.0

0.5

Dialysis

1.1

P200G5

PEG200-lignin

3.0

0.2

Dialysis

0.4

P200G6

PEG200-lignin

3.0

1.0

Neutralization

1.8

P400G

PEG400-lignin

3.0

1.0

Neutralization

2.0

P600G

PEG600-lignin

3.0

1.0

Neutralization

2.0

F1Ga

Fraction 1a

0.2

0.2

Neutralization

3.5

F2Ga

Fraction 2a

0.2

0.2

Neutralization

3.5

F3Ga

Fraction 3a

0.2

0.2

Neutralization

3.5

F4Ga

Fraction 4a

0.2

0.2

Neutralization

3.9

  1. aPEG200-lignin was fractionated by gradient acid precipitation at pH 10 (Fraction 1), pH 9.5 (Fraction 2), pH 7 (Fraction 3) and pH 2 (Fraction 4). F1G, F2G, F3G and F4G were prepared from Fraction 1, 2, 3 and 4, respectively