Official Journal of the Japan Wood Research Society
Table 2 CT-dependence of Mössbauer parameters at 298 K of iron-loaded charcoal samples
Sample | Type of split | IS (mm/s) | QS (mm/s) | H (T) | LW (mm/s) | Yield (%) | Iron species |
|---|---|---|---|---|---|---|---|
Fe3-300-1 | Doublet | 0.419 (4) | 0.971 (7) | ‒ | 0.55 (1) | 100 | High-spin Fe3+ |
Fe3-600-1 | Doublet | 0.340 (3) | 0.893 (4) | ‒ | 0.718 (7) | 100 | High-spin Fe3+ |
Fe3-650-1 | Doublet | 0.348 (2) | 0.929 (4) | ‒ | 0.699 (7) | 100 | High-spin Fe3+ |
Fe3-700-1 | Sextet-1 | − 0.003 (5) | 0 .02 (1) | 33.00 (3) | 0.28 (1) | 22 (1) | α-Fe |
Singlet | − 0.09 (2) | ‒ | ‒ | 0.28 (4) | 3 (1) | γ-Fe | |
Sextet-2 | 0.185 (3) | 0.032 (7) | 20.70 (3) | 0.36 (1) | 42 (1) | Fe3C | |
Doublet | 0.34 (1) | 0.89 (2) | ‒ | 0.86 (4) | 33 (1) | High-spin Fe3+ | |
Fe3-750-1 | Sextet-1 | 0.001 (3) | − 0.002 (6) | 33.06 (2) | 0.334 (8) | 34 (1) | α-Fe |
Singlet-1 | − 0.095 (1) | ‒ | ‒ | 0.321 (7) | 30 (1) | γ-Fe | |
Sextet-2 | 0.17 (1) | 0.05 (2) | 20.54 (8) | 0.35 (3) | 11 (1) | Fe3C | |
Singlet-2 | 0.17 (3) | ‒ | ‒ | 1.47 (7) | 25 (1) | High-spin Fe3+ | |
Fe3-800-1 | Sextet-1 | 0.002 (4) | − 0.008 (7) | 33.12 (2) | 0.339 (9) | 18.8 (4) | α-Fe |
Singlet-1 | − 0.098 (2) | ‒ | ‒ | 0.400 (6) | 20.0 (3) | γ-Fe | |
Sextet-2 | 0.188 (1) | 0.026 (3) | 20.67 (1) | 0.379 (4) | 54.7 (4) | Fe3C | |
Singlet-2 | 0.61 (2) | ‒ | ‒ | 0.90 (7) | 6.5 (5) | High-spin Fe3+ | |
Fe3-850-1 | Sextet-1 | 0.005 (4) | 0.010 (9) | 33.07 (3) | 0.35 (1) | 35 (1) | α-Fe |
Singlet-1 | − 0.099 (5) | ‒ | ‒ | 0.41 (3) | 23 (3) | γ-Fe | |
Sextet-2 | 0.187 (6) | 0.02 (1) | 20.80 (4) | 0.37 (2) | 28 (1) | Fe3C | |
Singlet-2 | 0.22 (8) | ‒ | ‒ | 0.99 (8) | 14 (4) | High-spin Fe3+ |