Employing a mixture of fine-particle PKS, glycerol, and citric acid as an eco-friendly binder for plywood production from rubberwood (Hevea brasiliensis) veneer

Abstract

Biomass-based adhesives, which are environmentally friendly and sustainable materials enabling low formaldehyde wood composites, have garnered interest. Therefore, palm kernel shells (PKS), available as industrial agricultural residue and rich in lignin, are mixed in form of fine particles with glycerol and citric acid, and tested as a candidate for binder in plywood production. The study focused on examining the effects of two factors: the quantity of adhesive used and the pressing temperature. Glycerol and citric acid are low-cost non-toxic chemicals that activate the functional groups and induce changes in the PKS component during hot pressing. Consequently, the mixtures with PKS as fine particles could cross-link with rubberwood veneer, forming a plywood panel with shear strength and bending strength that meet the requirements outlined in ISO 12466-2: part 2, and in Thai industrial standard (TIS 178-2549) for indoor use. The properties of plywood were primarily influenced by the pressing temperature rather than by the quantity of adhesive. Specifically, the temperatures 180 °C and 200 °C enhanced the extent to which the molten binder penetrated the rubberwood surface, consequently improving the mechanical properties and water resistance of the bonding.

Introduction

Plywood, a type of wood-based composite panels, has consistently been embraced by consumers as an excellent material for building construction, as well as for furniture or packaging. The growth potential in plywood manufacturing as well as for other wood composites is dependent on the stringent limits to environmental impacts. Specifically, concerns arise regarding formaldehyde emissions from the binders used. Hence, various bonding techniques and formaldehyde-free adhesives have been under investigation [1].

The cross-linking to form a panel of wood veneer layers, or of other shapes such as particles and fibers, primarily occurs through the combined effects of heat, moisture, and compression. This technique is referred to as self-bonding or binderless manufacturing [2,3,4]. All chemical components in wood or other lignocellulosic raw materials, mainly lignin, hemicellulose, and cellulose, along with various extractive components, influence the bonding strength of the resulting binderless board product. Additionally, the network of lignin and furan products, formed through the conversion of sugar monomers from carbohydrate polymers, enhances the bonding strength [5, 6]. Building upon these findings, wood and other lignocellulosic materials in the form of fine particles have also been utilized as natural adhesives in the production of veneer laminate boards. Kenaf (Hibiscus cannabinus L.) core powder, with a grain size of 10 μm, that was directly applied on the veneer surface before assembly and the hot compression process, was demonstrated in fabricating three-ply sugi (Cryptomeria japonica D. Don) plywood when subjected to hot pressing at 5 MPa pressure and 200 °C for a duration of 20 to 30 min [7]. On the other hand, the central portion of the oil palm trunk, rich in carbohydrate polymers such as starch and holocellulose, provides an opportunity for bonding with rubberwood veneer when hot pressed at 180 °C to 200 °C for a short 5 min pressing time. The bond strengths in both dry and wet conditions were improved when blended with citric acid [8]. Besides the use of fine particles, also chemicals extracted from lignocellulose materials, such as lignin and tannin, are still developed for plywood manufacturing [9]. Yang et al. [9] found that milled wood lignin (MWL) isolated from eucalyptus wood particles exhibits an excellent bonding performance when used to bond plywood from poplar veneers. Hot pressing at 190 °C and 1.5 MPa for 8 min gave a good bond strength surpassing the standard requirement of 0.7 MPa. Although isolated lignin holds potential for use as adhesive in plywood production, the extraction incurs prohibitive costs. Therefore, the utilization of lignocellulose materials in the form of fine particles as wood adhesives is comparatively attractive. This approach aligns with the desired adhesive properties: non-toxicity, affordability, a simple manufacturing process, a long shelf life, and ease of use. Importantly, the raw material should be continuously available on a commercial scale. In Southeast Asia, countries such as Indonesia, Malaysia, and Thailand have easy access to palm oil industrial residues, including empty fruit bunches (EFB), mesocarp fibers, and palm kernel shells (PKS). These biomass residues are primarily used as fuel in energy plants. Considering their chemical compositions, PKS stands out as an excellent source of lignin, containing around 45.5% lignin, 17.5–24.1% hemicellulose, and 24.6–29.9% cellulose [10, 11]. Unfortunately, the direct utilization of fine particles of lignocellulose as an adhesive results in a poor water resistance, along with the lignin exhibiting a lower reactivity than carbohydrate polymers such as hemicellulose and cellulose. Therefore, its bonding ability is improved with other chemicals [7, 12].

A previous study has reported the use of citric acid and glycerol with active functional groups as such modifiers. Citric acid possesses three carbonyl groups, while glycerol has three hydroxyl groups. Interestingly, both citric acid and glycerol are non-toxic and affordable chemicals; they are currently considered as renewable raw materials for the synthesis of formaldehyde-free wood adhesives [13, 14]. Citric acid in pure form, or in combination with glycerol and other chemicals such as glucose or tannin, has given good bonding results in plywood production [15, 16]. At elevated temperatures surpassing the melting point of citric acid, esterification occurs between the carboxyl groups in the citric acid and hydroxy groups in the glycerol as well as in wood polymers, encompassing both lignin and carbohydrates. In the case of lignin, cross-linking presents an opportunity for esterification to take place at the γ position in the β-O-4 and β-5 linkages, as well as at the hydroxy group in its aromatic structure. Carbohydrate polymers, including cellulose, hemicellulose, and starch, undergo reactions particularly yielding furan products that further cross-link with citric acid to form a bond network [17,18,19]. Azerêdo et al. [13] reported that an adhesive synthesized from glycerol and citric acid in the presence of tin (II) 2-ethylhexanoate as the catalyst, was preheated at 120 °C for 10 min before application at 150 g/m². The pair of veneers with the adhesive was then compressed at 120 °C and 2 MPa for 20 h. This gave a shear strength of 2.3 MPa for the bond between two plies of eucalyptus species (Eucalyptus sp.). In addition to their use as wood adhesives, citric acid and glycerol also excel in functioning as plasticizers of lignin and other composite polymers.

Therefore, the goal of this study was investigating the ability of a fine-particle binder mixture of palm kernel shell, glycerol, and citric acid to bond plywood. The study examined experimentally the impacts of adhesive quantity (g/m²) and pressing temperature, while maintaining a fixed pressure of 5 MPa and a pressing time of 10 min, on bonding performance and other properties of the resulting plywood.

Materials and methods

Materials

PKS residues from palm oil extraction were sourced from industries in Surat Thani province, located in southern peninsular Thailand. The PKS raw material underwent purification to remove contaminants such as tiny fibers and sand. Afterward, it was cleaned and dried at the low 50 °C temperature for 24 h. The dried PKS was then ground into fine particles using an electric grain mill (Rukthai locally made machine, Thailand). The particles that passed through a 0.10 mm sieve were used in this study. Glycerol and citric acid, both of analytical grade, were used without further purification. The conditioned rubberwood veneers, prepared using the rotary-cut method, had dimensions of 350 × 350 mm and an average thickness of 1.5 ± 0.2 mm. The average moisture content was approximately 11% for plywood production.

Preparation of PKS powder adhesive

To prepare a bio-based wood adhesive with fine solid particulates, the process began by dissolving in water 15% of citric acid based on the oven-dry weight of PKS. The amount of distilled water was determined to achieve the target moisture content of 30% in the blend with PKS. Once the citric acid was completely dissolved, glycerol was added in a 1:3 (w/w) ratio to PKS with continuous stirring until a clear solution formed. The acidic solution of glycerol was sprayed onto the pulverized PKS, and then the blend was kept in a covered beaker at room temperature for 1 h before use as a binder.

The thermal behavior was determined through thermogravimetric (TG) analysis and differential scanning calorimetry (DSC). In both samples, consisting of the PKS raw material and its mixture with glycerol and citric acid, approximately 5 g underwent decomposition characterization by TG analysis conducted with a TGA-Q500 apparatus. The samples were heated under identical conditions in an air atmosphere, from 50 to 600 °C at a heating rate of 10 °C/min. Furthermore, the two samples were analyzed using DSC analysis (Mettler-Toledo, Switzerland) by heating from 50 to 300 °C. The temperature was increased at a rate of 10 °C/min under nitrogen flushing with a flow rate of 20 mL/min.

Plywood preparation

To assess the performance of PKS mixed with glycerol and citric acid in plywood fabrication, the effects of the adhesive quantity per bond area (120, 160, and 200 g/m²) and pressing temperature (160, 180, and 200 °C) on plywood properties were studied. Different amounts of the blended PKS powder were applied to the surface of conditioned rubberwood veneer by a shaking stainless screen. The three layers of veneers, assembled with blended PKS powder, were compressed using a laboratory hot press to create the plywood board under a fixed maximum pressure of 5 MPa for 10 min at various pressing temperatures. Each treatment was done with five replications. All finished plywood boards were kept at room temperature for a few days before cutting of test specimens.

Bonding performance analysis

The specimen size and testing method for measuring the tensile shear strength, which was used to determine the bondability of PKS mixed with glycerol and citric acid, were adapted from ISO 12466-1: part 1 and ISO 12466-2: part 2 [20, 21]. The tensile shear strength of each plywood board was evaluated under both dry and wet conditions using a universal testing machine (10ST, Tinius Olsen, UK) equipped with a 5kN load cell at a constant crosshead speed of 3 mm/min. In the dry condition, the conditioned specimens were tested directly for tensile strength. In the wet condition, the specimens were soaked in cold water at 20 ± 3 °C for 24 h before undergoing testing. The tensile shear strength for both conditions was calculated as the maximum load (N) divided by the shear support area (mm²). The percentage of wood failure was visually evaluated in accordance to ISO 12466-1: plywood bonding quality part 1 [20]. Both testing conditions were applied to five samples taken from each plywood board.

The characterizations of bondline area in rubberwood plywood was assessed by stereo microscope (ZEISS Stemi 508). The changes in functional groups of PKS mixed with glycerol and citric acid were investigated before and after curing under the hot pressing at 200 °C for 10 min by Fourier transform infrared spectroscopy (FT-IR). The cured binder, obtained from the bond area between the laminates of the plywood specimen after testing the shear tensile strength in dry and wet conditions, was redried at a low temperature of 50 °C until it reached a constant weight before analyzing the functional groups. The same procedure was applied to the original PKS raw material and to a mixture of PKS, glycerol, and citric acid. Then, all the redried specimens were ground into fine particles and combined with potassium bromide (KBr) in a ratio of 1:35 before being subjected to a Vector 70 FT-IR spectroscope (Bruker, Germany). Scanning was performed in the range from 4000 to 400 cm⁻¹ with 32 scans per spectrum.

Testing other mechanical and physical properties

Each plywood board was cut into a suitable specimen size for physical and mechanical property testing, and the specimens were kept in a conditioning chamber with controlled 65% relative humidity and 20 °C temperature, until they reached a constant weight. The physical properties determined were density, water absorption (WA) and thickness swelling (TS), which were evaluated using the same specimen size with 50 mm (width) × 50 mm (length) × thickness of board. The weight and dimensions of each specimen were measured before and after immersing in cold water at 21 ± 3 °C for 2 and 24 h. The density testing was performed with two specimens per board, while water absorption and thickness swelling testing were conducted with three specimens per board.

The specimens in parallel to the grain of the veneer’s surface layer, had dimensions of 50 mm (width) × 200 mm (length) and the board thickness was used for determining the modulus of rupture (MOR) and modulus of elasticity (MOE) in a three-point bending test. Specimens were fixed on the support span of the Universal testing machine before applying a load with a fixed 10 mm/min head speed until the specimen failed. Each plywood board was tested with two specimens.

Formaldehyde emissions of plywood

The rubberwood veneer was of ordinary industrial type, and these plywood panels were bonded with a mixture of PKS, glycerol, and citric acid. This bonding occurred at various pressing temperatures and a maximum pressure of 5 MPa for 10 min, with the adhesive amount fixed at 200 g/m². These specimens were used for analyzing formaldehyde emissions according to the perforator method [22].

Results and discussion

The thermal properties of PSK fine particles mixed with glycerol and citric acid

The thermal degradation of the green adhesive prepared from PKS mixed with glycerol in a 3:1 (w/w) ratio, along with 15% citric acid based on the amount of PKS, was compared to the PKS original material for responses to thermogravimetric analysis (TGA) and differential thermogravimetry (DTG), as presented in Fig. 1. Clearly the glycerol and citric acid activated the degradation of PKS, as the TGA curve showed larger weight loss than for pure original PKS. The weight loss of PKS was rapid in the temperature range from 254 to 414 °C, exhibiting a high degradation rate with two peaks on the DTG curve at 278 °C and 363 °C. The high peak at 278 °C is mainly associated with thermal decomposition of hemicellulose and amorphous cellulose, while the peak at 363 °C mainly corresponds to lignin [23]. Huang et al. [24] found that the isolated lignin of PKS had a high decomposition rate at 280 °C and 373 °C. In the case of PKS mixed with glycerol and citric acid, the TGA curve continually decreased from around 122 °C to 417 °C, indicating a high decomposition rate across three temperature ranges on the DTG curve. The first stage, occurring from 122 to 221 °C with the highest peak at 173 °C, was related to the degradation of citric acid [25]. The second temperature range, from 221 to 337 °C, corresponded to the thermoset polymer products formed through the esterification of citric acid and glycerol [19]. Glycerol decomposes at around 290 °C [26]. The temperature response can also be complicated by the degradation of PKS components, and the last stage occurs from 337 to 417 °C with a peak at 317 °C.

Fig. 1

TGA/DTG responses

Figure 2 presents the DSC analysis of PKS blended with glycerol and citric acid compared to the original PKS powder. Both samples had an endothermic peak at similar ranges of temperature. However, the PKS blended with glycerol and citric acid had the highest peak at around 92 °C, and this was shifted to 87 °C in the case of the original PKS powder. This was due to the citric acid that normally shows melting at 153–155 °C, and retarded the melting point of PKS [27]. The tiny broad peak around 223 °C is related to decomposition of citric acid and esterified product of glycerol and citric acid [19]. Furthermore, the activation energy for melting was reduced from 383 J/g to 176 J/g when glycerol and citric acid were added. This was due to the plasticizing function of glycerol and citric acid [28].

Fig. 2

The DSC curve

The bonding characterization of plywood

The fine particles of PKS, when mixed with glycerol and citric acid, are a candidate for bonding rubberwood veneer to fabricate plywood, and the performance was assessed through tensile shear strength testing, as depicted in Fig. 3. The results indicate that, in the case of dry condition testing, the bonding performance of PKS mixed with glycerol and citric acid was significantly influenced by both the quantity of adhesive used and the pressing temperature (p < 0.05). It was observed that increasing both parameters improved the dry tensile shear strength of plywood. However, only the pressing temperature significantly affected the increase in wet tensile shear strength. Applying temperatures of 180 °C and 200 °C enhanced the water resistance of the bondline, thereby increasing the wet tensile shear strength of plywood. Unfortunately, a pressing temperature of 160 °C resulted in relatively lower average shear strength in dry condition testing, and all the plywood samples experienced delamination during a 24-h water soaking test. This is likely a result of inadequate heat and pressing duration, which may not have been sufficient to initiate and complete the esterification process between citric acid and the hydroxy groups found in glycerol and/or the wood polymer. It is worth noting that the esterification of citric acid with other compounds typically occurs at its melting point, which is around 155 °C [19]. This fact also provides an explanation for why applying pressing temperatures of 180 °C and 200 °C enhanced the shear strength in wet condition testing of plywood. The percentage of wood failure, related to the tensile shear strength, was approximately 40% when using pressing temperatures of 180 °C and 200 °C for all binder quantities studied in case of dry condition testing. The wet condition testing gave wood failure in the range from 20 to 30% accordance to ISO 12466-1: plywood bonding quality part 1. The highest dry tensile shear strength was 1.13 MPa achieved with binder quantity of 200 g/m² and a pressing temperature of 200 °C. However, under these conditions, the tensile shear strength decreased by 52% after soaking in water for 24 h, resulting in a wet tensile shear strength of 0.53 MPa.

Fig. 3

The tensile shear strength of plywood bonded with PKS mixed with glycerol and citric acid, compressed at 160 °C, 180 °C or 200 °C when applying an adhesive quantity in the range from 120 to 200 g/m²

Typically, the bond strength is affected by the degree of adhesive penetration in the interphase region. Figure 4 presents photographs of the bond area within the veneer layer of the plywood structure, after hot pressing in various conditions that were studied. The results clearly demonstrate that when pressing at 160 °C was employed, the adhesive penetration was shallower compared to those at 180 °C and 200 °C. Penetration is characterized by a distinct dark-brown color observed through visual inspection. The observed effect is likely a result of the high heat which promoted the melting of components in PSK mixed with glycerol and citric acid, allowing for a deeper thorough penetration into the rubberwood veneer. Furthermore, the PKS components in presence of glycerol and citric acid might be liquefied to small substages that further move between particles and rubberwood surfaces. In thermal-acidic conditions, lignin and hemicellulose are easily converted to liquor products, and the rate of this conversion reaction is accelerated by elevating the temperature [29]. Hence, it is conceivable that the chemical components of rubberwood were also degraded, particularly in the interphase region. All these factors collectively contributed to the improvement in bond strength.

Fig. 4

Photographs of bonding between layers in cross-sections of rubberwood plywood

Figure 5a presents the FT-IR spectra of original PKS raw material, the binder mixture of PKS, glycerol and citric acid, including the cured binder taken from the dry and wet condition of the shear tensile strength testing specimens. Upon examination of the PKS mixed with glycerol and citric acid for its spectral patterns, the addition of glycerol and citric acid to the PKS promoted some functional groups, especially the hydroxyl groups (–OH) and the carboxylic groups (–COOH). These two functional groups exhibit a great ability to bond with wood polymers. The O–H stretching exhibited a broader spectrum around 3401 cm⁻¹ in the FT-IR analysis of PKS mixed with glycerol and citric acid, which is slightly shifted from the PKS original material that exhibited a peak around 3399 cm⁻¹. Meanwhile, the C=O stretching and C–O stretching in carboxylic groups (–COOH) are represented by distinct peaks around 1736 cm⁻¹ and 1239 cm⁻¹, respectively. The peak at 1736 cm⁻¹ overlaps with the C=O stretching found in the structure of hemicellulose and lignin [30]. Interestingly, the strong peaks corresponding to the O–H stretching and the C=O stretching were reduced in both cases of the cured binder. This observation corroborates the polycondensation of PKS components with glycerol and/or citric acid, as well as with rubberwood polymers. Citric acid contains three carboxylic groups esterified with the hydroxy groups of glycerol and/or wood polymers to form the ester product, showing the carbonyl ester overlap with the C=O stretching of PKS component, as well as the C=O stretching in the citric acid structure [31]. In addition, the peak around 1635 cm⁻¹ that corresponded to the citric acid structure was clearly reduced after the binder was cured. The FT-IR spectrum of glycerol does not show a peak around 1736 cm⁻¹, but it reveals the peak of O–H stretching around 3322 cm⁻¹ [32]. According to a previous study, using citric acid and glycerol as a binder in particleboard production forms ester linkages, shown around 1731 cm⁻¹, improving the water resistance of the board [31]. Ando and Umemura [18] found that the carbonyl peak of esterification between citric acid and wood polymer was around 1740 cm⁻¹. Hence, the ester bond was possibly shifted to 1736 cm⁻¹ in this study. This is supported by the FT-IR spectrum around 1736 cm⁻¹ of the cured binder from wet condition testing that had stronger peaks than in the spectrum of PKS original material. Normally, the ester linkages formed by citric acid can resist water [31].

Fig. 5

The FT-IR spectra (a), and potential bonding reactions of plywood (b)

From the data above and the review of prior literature, it is apparent that the bonding reaction between the binder components and the rubberwood veneer was complicated. Figure 5b indicates the potential bonding reaction of plywood. It was possibly supported by hydrogen bonding between hydroxy groups present in both PKS and rubberwood [3]. Ester linkages formed as the three carboxylic groups of citric acid reacted with hydroxy groups in glycerol and with the polymer structures of PKS and rubberwood [13, 15, 18]. Additionally, the acidic solution of glycerol and citric acid that penetrated into PKS and rubberwood likely activated liquefaction reactions, converting components into smaller molecular weight compounds such as sugar monomers, which further transformed into furan products such as furfural or 5-HMF during hot compression. Furan products could also cross-link with free functional groups of citric acid, and with components of PKS and rubberwood. Furthermore, glycerol could undergo etherification with lignin and other degraded carbohydrate polymers [18, 19, 29, 33]. Ether bonding (C–O–C stretching) was observed from a peak in the range from 1070 to 1250 [34], which likely overlapped with the spectra of PKS.

Other mechanical and physical properties of plywood

Static 3-point bending strength was employed to evaluate the MOR and MOE of plywood bonded under various conditions with a mixture of fine particles of PKS, glycerol, and citric acid. The results are presented in Fig. 6. The pressing temperature significantly (p < 0.05) affected the MOR and MOE of plywood, while the adhesive quantity did not show significant effects on these properties. Plywood showed an increased MOR with higher pressing temperatures. The highest MOR was achieved when the pressing temperature was set at 200 °C. Visually it was observed that the failures of plywood during bending were often due to cracking at the bonded interface. This indicates that the bending strength of plywood is supported by bonding strength. Furthermore, the densification and chemical changes of the rubberwood veneer's surface layer resulting from hot pressing can also enhance the mechanical properties of plywood [35, 36].

Fig. 6

The MOR and MOE of plywood bonded with PKS mixed with glycerol and citric acid, compressed at 160 °C, 180 °C or 200 °C when applying an adhesive quantity in the range from 120 to 200 g/m²

Table 1 summarizes the physical properties of plywood bonded with PKS mixed with glycerol and citric acid. The results reveal that the factors pressing temperature and adhesive quantity did not significantly affect the density, TS, or WA of plywood. The veneer layers of all plywood samples hot pressed at 160 °C separated (delaminated) when immersed in water. This means that the cross-linking was not sufficiently strong to resist the ingress of water molecules, particularly as hydrogen bonds might be formed by the self-bonding of PKS and/or rubberwood, and the binder was not completely cured. Furthermore, using higher pressing temperatures in the range from 180 to 200 °C not only facilitated the esterification of citric acid and glycerol but also promoted the degradation of wood polymers, especially hemicellulose. Hemicellulose typically possesses a high water-absorption capacity [37]. Consequently, employing high pressing temperatures might cause the degradation of hemicellulose and thus enhance the water resistance of plywood. The average moisture content of plywood was significantly influenced by pressing temperature (p < 0.05), with a slight reduction observed in the case of a 200 °C pressing temperature. The densification of rubberwood veneer during hot compression under a maximum pressure of 5 MPa resulted in high-density plywood compared to the density of rubberwood veneer (0.619 ± 0.016 g/cm³). The compression ratio was approximately 17% based on the uncured board. Pressing temperatures in the range from 180 to 200 °C could maintain the form of plywood, resulting in TS ranging from 4.91 to 6.02% and WA ranging from 23.81 to 30.77% after soaking in water for 2 h. Unfortunately, both values increased when soaking for 24 h, but they were lower than in a previous report [15].

Table 1 The influences of pressing temperature and adhesive quantity on the physical properties of plywood bonded with PKS mixed with glycerol and citric acid

Formaldehyde emissions from plywood

Originally, wood and other lignocellulose materials contain small amounts of formaldehyde, with the concentration depending on the wood species and the heat treatment done [38]. The rubberwood veneer raw material showed a formaldehyde emission of 0.71 mg/100 g, which is close to the formaldehyde concentration in mature wood of Scots pine (Pinus sylvestris L.) [39]. Formaldehyde can be generated from extractives, lignin, and carbohydrate polymers in wood during hot pressing [40]. Therefore, plywood bonded with 200 g/m² of PKS mixed with glycerol and citric acid revealed formaldehyde emissions of 0.81 mg/100 g and 1.05 mg/100 g for pressing temperatures of 180 °C and 200 °C, respectively. However, those formaldehyde emissions from plywood products were compliant with the standard requirement for wood composite products (≦ 8 mg/100 g).

Conclusion

The thermal degradation of PKS fine particles was accelerated by the addition of glycerol and citric acid. According to DSC analysis, the natural binder composed of a mixture of PKS, glycerol, and citric acid required a comparatively low activation energy to soften under heat. However, the esterification reaction of citric acid or glycerol cross-linked the fine particles of PKS and rubberwood, and this required elevated pressing temperatures in the range from 180 to 200 °C for the creation of plywood with excellent tensile shear strength, strong mechanical properties, and water resistance of bondline. Based on the parameters of this study, the plywood bonded with a mixture of fine particles of PKS, glycerol, and citric acid has the potential to be classified as indoor grade according to both the ISO 12466-2: Part 2 and the TIS 178-2549 standard. It is recommended to use adhesive quantities of 160 and 200 g/m² with a pressing temperature of 180 °C, and 120 to 200 g/m² with a pressing temperature of 200 °C, to bond the rubberwood veneer.